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If the reactions take place within a vessel, the high temperature may increase the vessel pressure to the point that it ruptures or explodes. All compressed gases are potentially hazardous since they are under great pressure in a container. Accidental rupture of the container and the rapid release of the pressurized gas can result in injury to persons and damage to objects in the vicinity. Not only can the gas be released with great force, but the force of the release may propel the container for a long distance. In addition to the mechanical hazard from the pressure or propelled container, other hazards may exist from the released gas.
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The hazard determination for these chemicals may be more involved since reliable data compilations may not exist. The determination in this case requires a more exhaustive search for information. If a mixture has not been tested as a whole to determine whether the mixture is a physical hazard, the chemical manufacturer or importer may use whatever scientifically valid data are available to evaluate the physical hazards of the mixture. The definition for hazardous chemical in the standard is thus very broad, and it is not likely that many chemicals will be considered non-hazardous if they have been adequately tested. However, the standard does not require the testing of chemicals – only the collection and analysis of currently available data.
Some chemicals may be oxidizers with such an extremely fast burning potential that they are classified as explosives or blasting agents rather than oxidizers. Often the fact that a chemical possesses oxidizing potential can be determined by an examination of its chemical structure.
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Thus, the initial step is to collect as much data as possible pertaining to the physical and chemical properties and toxicity data for chemicals on your chemical inventory. For most of the chemicals specifically designated as hazardous in the HCS, the available information has been compiled in readily available and reliable sources . If a chemical is not specifically designated as hazardous, you must collect and evaluate the data and determine if the chemical is hazardous.
Testing should be considered if hazardous properties are suspected. Eye hazard For a hazard determination to be complete, one must consider all possible hazards, and document any hazards that are identified.
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The hazard from some compressed gases may be strictly mechanical (e.g. , compressed air), others may possess other types of hazards, such as being flammable (e.g. , methane and propane) or toxic (e.g. , ammonia and chlorine). Oxidation materials can initiate or greatly accelerate the burning of fuels. Oxygen-containing chemicals (e.g. , hydrogen peroxide and nitrous oxide) and halogens (e.g. , bromine, chlorine, and fluorine) can also be strong oxidizers.